Sample preparation of PFAS from Food according to FDA Method C-010.02
Sample preparation of PFAS from Food according to FDA Method C-010.02
Sample preparation of PFAS from Food according to FDA Method C-010.02
Sample preparation of PFAS from Food according to FDA Method C-010.02
Sample preparation of PFAS from Food according to FDA Method C-010.02
- Application Number
- 306840
- Method
- SPE
- Results
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Legend: Recovery rates (1/2)
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Legend: Recovery rates (2/2)
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- Substances
- PFAS: PFBA (Perfluorobutanoic acid); PFPeA (Perfluoropentanoic acid); HFPO-DA (2,3,3,3-Tetrafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy) propanoic acid (GenX)); FBSA (Perfluorobutanesulfonamide); L-PFBS (Perfluorobutanesulfonic acid); PFHxA (Perfluorohexanoic acid); 4:2 FTS (Sodium 1H,1H,2H,2H-perfluorohexanesulfonate); L-PFPes (Perfluoropentanesulfonic acid); PFHpA (Perfluoroheptanoic acid); NaDONA (Sodium dodecafluoro-3H-4,8-dioxanonanoate); FHxSA (Perfluorohexanesulfonamide); PFHxSK (Perfluorohexanesulfonic acid); PFOA (Perfluorooctanoic acid); 6:2 FTS (Sodium 1H,1H,2H,2H-perfluorooctanesulfonate); PFHpS (Perfluoroheptanesulfonic acid); PFNA (Perfluorononanoic acid); FOSA (Perfluorooctanesulfonamide); PFOSK (Perfluorooctanesulfonic acid); PFDA (Perfluorodecanoic acid); 8:2 FTS (Sodium 1H,1H,2H,2H-perfluorodecanesulfonate); 9Cl-PF3ONS (Potassium 9-chlorohexadecafluoro-3-oxanonane-1-sulfonate); L-PFNS (Sodium perfluorononanesulfonate); PFUdA (Perfluoroundecanoic acid); N-MeFOSAA (N-methylperfluorooctanesulfonamidoacetic acid); N-EtFOSAA (N-ethylperfluorooctanesulfonamidoacetic acid); PFDS (Sodium perfluorodecanesulfonate); PFDoA (Perfluorododecanoic acid); 11Cl-PL3OUdS (11-chloroeicosafluoro-3-oxaundecane-1-sulfonic acid); PFTrDA (Perfluorotridecanoic acid); PFTeDA (Perfluorotetradecanoic acid; M4PFBA (Perfluoro-(13C4)butanoic acid); M5PFPeA (Perfluoro-(13C5)pentanoic acid); M3PFBS (Sodium perfluoro-(2,3,4-13C3)butanesulfonate); M5PFHxA (Perfluoro-(1,2,3,4,6-13C5)hexanoic acid); M2-4:2FTS (Sodium 1H,1H,2H,2H-perfluoro(1,2-13C2)hexanesulfonate); M4PFHpA (Perfluoro-(1,2,3,4-13C4)heptanoic acid); M3PFHxS (Sodium perfluoro-(1,2,3-13C3)hexanesulfonate); M8PFOA (Perfluoro-(13C8)octanoic acid); M2-6:2FTS (Sodium 1H,1H,2H,2H-perfluoro(1,2-13C2)octanesulfonate); M9PFNA (Perfluoro-(13C9)nonanoic acid); M8FOSA (Perfluoro-(13C8)octanesulfonamide); M8PFOS (Sodium perfluoro-(13C8)octanesulfonate; M6PFDA (Perfluoro-(1,2,3,4,5,6-13C6)decanoic acid; M2-8:2FTS (Sodium 1H,1H,2H,2H-perfluoro(1,2-13C2 )decanesulfonate); M7PFUdA (Perfluoro-(1,2,3,4,5,6,7-13C7)undecanoic acid); d3-N-MeFOSAA (N-methyl-d3-perfluorooctanesulfonamidoacetic acid); d5-N-EtFOSAA (N-ethyl-d5-perfluorooctanesulfonamidoacetic acid); MPFDoA (Perfluoro-(1,2-13C2)dodecanoic acid); M2PFTeDA (Perfluoro-(1,2-13C2 )tetradecanoic acid)
- Product(s)
Phase REF Webshop CHROMABOND QuEChERS Mix XII
730648
CHROMABOND QuEChERS Mix L
7300008
- Matrix
- food
- Sample(s)
- Conditions
Sample pretreatment
- Weigh amount of sample and LC/MS grade water based on Table 1 and commodity type into an empty 50 mL centrifuge tube (REF 730223)
- Add 0.1 mL of internal standard solution (0.1 µg/mL each compound in methanol) and 0.1 mL of native standard solution (0.1 µg/mL each compound in methanol) for determining recovery rate
- Shake the mixture for 1 min
- Add 9.8 mL acetonitrile and 150 μL formic acid
- Shake the mixture for 1 min
- Add CHROMABOND QuEChERS Mix XII (REF 730648)
- Shake the mixture for 1 min
- Centrifuge the mixture for 5 min at 4500 rpm at 5 °C
- Transfer 6 mL supernatant to a 15 mL centrifuge tube, which is prefilled with CHROMABOND QuEChERS Mix L (REF 7300008)
- Shake for 1 minute
- Centrifuge again for 5 min at 4500 rpm at 5 °C
- Supernatant is ready to be analyzed by LC/MS/MS (MN Appl. No. 129000)
- Detection
- MS/MS
- Subsequent analysis
- HPLC, see MN application 129000
- Note
- For further information, check out: www.mn-net.com/pfas
- Author
- Application department
- Source
- MACHEREY-NAGEL, Germany 2022
- Disclaimer
- Concerning questions to literature applications please contact the cited author/s. Chemicals mentioned in applications are not manufactured or sold by MACHEREY-NAGEL. Applications mentioned in MACHEREY-NAGEL literature or databases are provided for informational purposes only. MACHEREY-NAGEL does not warrant that all applications have been tested in MACHEREY-NAGEL laboratories using MACHEREY-NAGEL products. MACHEREY-NAGEL does not warrant the correctness of the applications.
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