Determination of selected polyfluorinated compounds (PFC) in water acc. to DIN 38407-42

Determination of selected polyfluorinated compounds (PFC) in water acc. to DIN 38407-42

Determination of selected polyfluorinated compounds (PFC) in water acc. to DIN 38407-42

Application Number
126530
Method
HPLC
Results

Legend:
X - time, min Y - signal intensity 1 - perfluorobutanoic acid (PFBA) 2 - perfluoropentanoic acid (PFPeA) 3 - perfluorobutanesulfonic acid (PFBS) 4 - perfluorohexanoic acid (PFHxA) 5 - perfluoroheptanoic acid (PFHpA) 6 - perfluorohexanesulfonic acid (PFHxS) 7 - perfluorooctanoic acid (PFOA) 8 - perfluorononanoic acid (PFNA) 9 - perfluorooctanesulfonic acid (PFOS) 10 - perfluorodecanoic acid (PFDA) 11 - perfluoroundecanoic acid (PFUnA) 12 - perfluorododecanoic acid (PFDoA) 13 - perfluoroheptanesulfonic acid (PFHpS) 14 - perfluorodecanesulfonic acid (PFDS) A - 13C4 perfluorobutanoic acid (13C4 PFBA) B - 13C2 perfluorohexanoic acid (13C2 PFHxA) C - 13C4 perfluorooctanoic acid (13C4 PFOA) D - 13C4 perfluorooctanesulfonic acid (13C4 PFOS)

Substances
perfluorobutanoic acid (PFBA); perfluoropentanoic acid (PFPeA); perfluorohexanoic acid (PFHxA); perfluoroheptanoic acid (PFHpA); perfluorooctanoic acid (PFOA); perfluorononanoic acid (PFNA); perfluorodecanoic acid (PFDA); perfluoroundecanoic acid (PFUnA); perfluorododecanoic acid (PFDoA); perfluorobutanesulfonic acid (PFBS); perfluorohexanesulfonic acid (PFHxS); perfluoroheptanesulfonic acid (PFHpS); perfluorooctanesulfonic acid (PFOS); perfluorodecanesulfonic acid (PFDS)
Product(s)
PhaseREFWebshop

NUCLEODUR C18 Pyramid

760260.20

NUCLEODUR C18 Pyramid

761916.20

Matrix
water
Sample(s)

SPE in reference to Appl. No. 305820

Conditions

Eluent A: 10 mmol/L ammonium acetate in water - methanol (75:25, v/v)

Eluent B: 10 mmol/L ammonium acetate in acetonitrile - methanol (75:25, v/v)

Gradient: 0 - 30 % B in 5 min, 30 - 55 % B in 8 min, 55 - 80 % B in 19 min

Flow rate: 0.3 mL/min

Temperature: 50 °C

Injection volume: 10 µL (each concentration: 10 ng/mL)

Detection
MS/MS-ESI
Note
Author
Normenausschuss Wasserwesen (NAW) im DIN
Source
DIN 38407-42:2011-03, Bestimmung ausgewählter polyfluorierter Verbindungen (PFC) in Wasser - Verfahren mittels HPLC-MS/MS nach Fest-Flüssig-Extraktion, Germany
Disclaimer
Concerning questions to literature applications please contact the cited author/s. Chemicals mentioned in applications are not manufactured or sold by MACHEREY-NAGEL. Applications mentioned in MACHEREY-NAGEL literature or databases are provided for informational purposes only. MACHEREY-NAGEL does not warrant that all applications have been tested in MACHEREY-NAGEL laboratories using MACHEREY-NAGEL products. MACHEREY-NAGEL does not warrant the correctness of the applications.
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